Google stopped the free Google apps(standard version). Still you can register free email for another domain using the old free Google apps Account.
- Login to your Google apps domain management.(www.google.com/a/cpanel/YOURDOMAIN/
- Select Domain Settings and then Domain names
- Click on the button Add domain or a domain name alias.
- Select Another domain and enter your domain there. Then click on Continue domain verification
- Verify the domain name by any of the method provided (Best one is txt method.)
- After verification, you can register email for that domain from the Dashboard
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